Identify A, B, C, D, E, R

Question:

Identify A, B, C, D, E, R and R1 in the following:

Solution:

Since D of D2O gets attached to the carbon atom to which MgBr is attached, C is

Therefore, the compound R − Br is

 

When an alkyl halide is treated with Na in the presence of ether, a hydrocarbon containing double the number of carbon atoms as present in the original halide is obtained as product. This is known as Wurtz reaction. Therefore, the halide, R1−X, is

Therefore, compound D is

And, compound E is

 

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