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A coordination compound CrCl3.4H2O precipitates silver

Question:

A coordination compound CrCl3.4H2O precipitates silver chloride when treated with silver nitrate. The molar conductance of its solution corresponds to a total of

two ions. Write the structural formula of the compound and name it.

Solution:

If it forms silver chloride then there is one free chlorine atom outside the coordination sphere. The structural formula has to be [Cr(H2O)4Cl2]Cl. The name of this complex is tetraaquadichlorido chromium(III) chloride.

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