A reaction is first order in A and second order in B.
(i) Write the differential rate equation.
(ii) How is the rate affected on increasing the concentration of B three times?
(iii) How is the rate affected when the concentrations of both A and B are doubled?
(i) The differential rate equation will be
$-\frac{d[\mathrm{R}]}{d t}=k[\mathrm{~A}][\mathrm{B}]^{2}$
(ii) If the concentration of B is increased three times, then
$-\frac{d[\mathrm{R}]}{d t}=k[\mathrm{~A}][3 \mathrm{~B}]^{2}$
$=9 \cdot k[\mathrm{~A}][\mathrm{B}]^{2}$
Therefore, the rate of reaction will increase 9 times.
(iii) When the concentrations of both A and B are doubled,
$-\frac{d[\mathrm{R}]}{d t}=k[\mathrm{~A}][\mathrm{B}]^{2}$
$=k[2 \mathrm{~A}][2 \mathrm{~B}]^{2}$
$=8 \cdot k[\mathrm{~A}][\mathrm{B}]^{2}$
Therefore, the rate of reaction will increase 8 times.