Expansion of gas in a vacuum is called

Question:

Expansion of gas in a vacuum is called free expansion. Calculate the work is done and the change in internal energy when 1 litre of an ideal gas expands isothermally into a vacuum until its total volume is 5 litre?

Solution:

Work done in vacuum is calculated by :

-w = Text (Vinitial – Vfinal )

Pext= 0

–w = 0x(5-1) = 0.

For isothermal expansion q=o

q= ∆U + (-w)

Hence ∆U will be 0.

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