Predict which of the following will be coloured in aqueous solution?

Question:

Predict which of the following will be coloured in aqueous solution? Ti3+V3+, Cu+Sc3+Mn2+, Fe3+ and Co2+. Give reasons for each.

Solution:

Only the ions that have electrons in d-orbital and in which d-d transition is possible will be coloured. The ions in which d-orbitals are empty or completely filled will be colourless as no d-d transition is possible in those configurations.

From the above table, it can be easily observed that only Sc3+ has an empty d-orbital and Cu+ has completely filled d-orbitals. All other ions, except Sc3+ and Cu+, will be coloured in aqueous solution because of dd transitions.

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