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Solution:

$\left[x \sin ^{2}\left(\frac{y}{x}\right)-y\right] d x+x d y=0$

$\Rightarrow \frac{d y}{d x}=\frac{-\left[x \sin ^{2}\left(\frac{y}{x}\right)-y\right]}{x}$                ...(1)

Let $F(x, y)=\frac{-\left[x \sin ^{2}\left(\frac{y}{x}\right)-y\right]}{x}$.

$\therefore F(\lambda x, \lambda y)=\frac{-\left[\lambda x \cdot \sin ^{2}\left(\frac{\lambda x}{\lambda y}\right)-\lambda y\right]}{\lambda x}=\frac{-\left[x \sin ^{2}\left(\frac{y}{x}\right)-y\right]}{x}=\lambda^{0} \cdot F(x, y)$

Therefore, the given differential equation is a homogeneous equation.

To solve this differential equation, we make the substitution as:

y = vx

$\Rightarrow \frac{d}{d x}(y)=\frac{d}{d x}(v x)$

$\Rightarrow \frac{d y}{d x}=v+x=\frac{d v}{d x}$

Substituting the values of $y$ and $\frac{d y}{d x}$ in equation (1), we get:

$v+x \frac{d v}{d x}=\frac{-\left[x \sin ^{2} v-v x\right]}{x}$

$\Rightarrow v+x \frac{d v}{d x}=-\left[\sin ^{2} v-v\right]=v-\sin ^{2} v$

$\Rightarrow x \frac{d v}{d x}=-\sin ^{2} v$

$\Rightarrow \frac{d v}{\sin ^{2} v}=-\frac{d x}{d x}$

$\Rightarrow \operatorname{cosec}^{2} v d v=-\frac{d x}{x}$

Integrating both sides, we get:

$-\cot v=-\log |x|-\mathrm{C}$

$\Rightarrow \cot v=\log |x|+\mathrm{C}$

$\Rightarrow \cot \left(\frac{y}{x}\right)=\log |x|+\log \mathrm{C}$

$\Rightarrow \cot \left(\frac{y}{x}\right)=\log |\mathrm{C} x|$          ...(2)

Now, $y=\frac{\pi}{4}$ at $x=1$

$\Rightarrow \cot \left(\frac{\pi}{4}\right)=\log |\mathrm{C}|$

$\Rightarrow \mathrm{I}=\log \mathrm{C}$

$\Rightarrow \mathrm{C}=e^{1}=e$

Substituting C = e in equation (2), we get:

$\cot \left(\frac{y}{x}\right)=\log |e x|$

This is the required solution of the given differential equation.