$0.01$ moles of a weak acid $\mathrm{HA}\left(\mathrm{K}_{\mathrm{a}}=2.0 \times 10^{-6}\right)$ is dissolved in $1.0 \mathrm{~L}$ of $0.1 \mathrm{M} \mathrm{HCl}$ solution. The degree of dissociation of HA is $\times 10^{-5}$ (Round off to the Nearest Integer). [Neglect volume change on adding HA. Assume degree of dissociation $<<1$ ]
$\mathrm{HA} \rightleftharpoons \mathrm{H}^{+}+\mathrm{A}^{-}$
Initial conc. $0.01 \mathrm{M} \quad 0.1 \mathrm{M} \quad 0$
Equ. conc. $(0.01-\mathrm{x})(0.1+\mathrm{x}) \mathrm{xM}$
$\approx 0.01 \mathrm{M} \approx 0.1 \mathrm{M}$
Now, $\mathrm{K}_{\mathrm{a}}=\frac{\left[\mathrm{x}^{+}\right]\left[\mathrm{A}^{-}\right]}{[\mathrm{HA}]} \Rightarrow 2 \times 10^{-6}=\frac{0.1 \times \mathrm{x}}{0.01}$
$\therefore \quad x=2 \times 10^{-7}$
Now, $\alpha=\frac{\mathrm{x}}{0.01}=\frac{2 \times 10^{-7}}{0.01}=2 \times 10^{-5}$
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All Study Material
- JEE Main
- Exam Pattern
- Previous Year Papers
- PYQ Chapterwise
- Physics
- Kinematics 1D
- Kinemetics 2D
- Friction
- Work, Power, Energy
- Centre of Mass and Collision
- Rotational Dynamics
- Gravitation
- Calorimetry
- Elasticity
- Thermal Expansion
- Heat Transfer
- Kinetic Theory of Gases
- Thermodynamics
- Simple Harmonic Motion
- Wave on String
- Sound waves
- Fluid Mechanics
- Electrostatics
- Current Electricity
- Capacitor
- Magnetism and Matter
- Electromagnetic Induction
- Atomic Structure
- Dual Nature of Matter
- Nuclear Physics
- Radioactivity
- Semiconductors
- Communication System
- Error in Measurement & instruments
- Alternating Current
- Electromagnetic Waves
- Wave Optics
- X-Rays
- All Subjects
- Physics
- Motion in a Plane
- Law of Motion
- Work, Energy and Power
- Systems of Particles and Rotational Motion
- Gravitation
- Mechanical Properties of Solids
- Mechanical Properties of Fluids
- Thermal Properties of matter
- Thermodynamics
- Kinetic Theory
- Oscillations
- Waves
- Electric Charge and Fields
- Electrostatic Potential and Capacitance
- Current Electricity
- Thermoelectric Effects of Electric Current
- Heating Effects of Electric Current
- Moving Charges and Magnetism
- Magnetism and Matter
- Electromagnetic Induction
- Alternating Current
- Electromagnetic Wave
- Ray Optics and Optical Instruments
- Wave Optics
- Dual Nature of Radiation and Matter
- Atoms
- Nuclei
- Semiconductor Electronics: Materials, Devices and Simple Circuits.
- Chemical Effects of Electric Current,