Which one of the following species doesn't have a magnetic moment of 1.73 BM, (spin only value) ?
$\mathrm{O}_{2}^{+}$
$\mathrm{CuI}$
$\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}$
$\mathrm{O}_{2}^{-}$
Correct Option: , 2
Species must not contain single unpaired
(1) $\mathrm{O}_{2}^{+} \rightarrow \sigma_{1 \mathrm{~s}}^{2}<\sigma_{1 \mathrm{~s}}^{* 2}<\sigma_{2 \mathrm{~s}}^{2}<\sigma_{2 \mathrm{~s}}^{* 2}<\sigma_{2 \mathrm{pz}}^{2}<\pi_{2 \mathrm{px}}^{2}=\pi_{2 \mathrm{py}}^{2}<\pi_{2 \mathrm{px}}^{* 1}=\pi_{2 \mathrm{py}}^{*}$
unpaired $\mathrm{e}^{-}=1 \therefore \mu=1.73 \mathrm{BM}$
(1) $\mathrm{Cu}^{+} \mathrm{I}^{-} \mathrm{Cu}^{+} \rightarrow[\mathrm{Ar}] 3 \mathrm{~d}^{10} \therefore$ unpaired $\mathrm{e}^{-}=0$
$\mathrm{I}^{-} \rightarrow[\mathrm{Xe}] \therefore$ unpaired $\mathrm{e}^{-}=0$
therefore $\mu=0$
3. $\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}$
$\mathrm{Cu} \rightarrow[\mathrm{A}] 3 \mathrm{~d}^{3} \therefore$ unpaired $=1 \therefore \mu=1.73 \mathrm{BM}$
4. $\mathrm{O}_{2}^{-} \rightarrow \mathrm{d}$
$\sigma_{1 \mathrm{~s}}^{2}<\sigma_{1 \mathrm{~s}}^{* 2}<\sigma_{2 \mathrm{~s}}^{2}<\sigma_{2 \mathrm{~s}}^{* 2}<\sigma_{2 \mathrm{px}}^{2}<\pi_{2 \mathrm{px}}^{2}=\pi_{2 \mathrm{py}}^{2}<\pi_{2 \mathrm{px}}^{* 1}=\pi_{2 \mathrm{py}}^{*}$
$\left(11 \mathrm{e}^{-}\right)$
$\therefore$ unpaired $\therefore \mu=1.73 \mathrm{BM}$
- JEE Main
- Exam Pattern
- Previous Year Papers
- PYQ Chapterwise
- Physics
- Kinematics 1D
- Kinemetics 2D
- Friction
- Work, Power, Energy
- Centre of Mass and Collision
- Rotational Dynamics
- Gravitation
- Calorimetry
- Elasticity
- Thermal Expansion
- Heat Transfer
- Kinetic Theory of Gases
- Thermodynamics
- Simple Harmonic Motion
- Wave on String
- Sound waves
- Fluid Mechanics
- Electrostatics
- Current Electricity
- Capacitor
- Magnetism and Matter
- Electromagnetic Induction
- Atomic Structure
- Dual Nature of Matter
- Nuclear Physics
- Radioactivity
- Semiconductors
- Communication System
- Error in Measurement & instruments
- Alternating Current
- Electromagnetic Waves
- Wave Optics
- X-Rays
- All Subjects
- Physics
- Motion in a Plane
- Law of Motion
- Work, Energy and Power
- Systems of Particles and Rotational Motion
- Gravitation
- Mechanical Properties of Solids
- Mechanical Properties of Fluids
- Thermal Properties of matter
- Thermodynamics
- Kinetic Theory
- Oscillations
- Waves
- Electric Charge and Fields
- Electrostatic Potential and Capacitance
- Current Electricity
- Thermoelectric Effects of Electric Current
- Heating Effects of Electric Current
- Moving Charges and Magnetism
- Magnetism and Matter
- Electromagnetic Induction
- Alternating Current
- Electromagnetic Wave
- Ray Optics and Optical Instruments
- Wave Optics
- Dual Nature of Radiation and Matter
- Atoms
- Nuclei
- Semiconductor Electronics: Materials, Devices and Simple Circuits.
- Chemical Effects of Electric Current,
All Study Material
- JEE Main
- Exam Pattern
- Previous Year Papers
- PYQ Chapterwise
- Physics
- Kinematics 1D
- Kinemetics 2D
- Friction
- Work, Power, Energy
- Centre of Mass and Collision
- Rotational Dynamics
- Gravitation
- Calorimetry
- Elasticity
- Thermal Expansion
- Heat Transfer
- Kinetic Theory of Gases
- Thermodynamics
- Simple Harmonic Motion
- Wave on String
- Sound waves
- Fluid Mechanics
- Electrostatics
- Current Electricity
- Capacitor
- Magnetism and Matter
- Electromagnetic Induction
- Atomic Structure
- Dual Nature of Matter
- Nuclear Physics
- Radioactivity
- Semiconductors
- Communication System
- Error in Measurement & instruments
- Alternating Current
- Electromagnetic Waves
- Wave Optics
- X-Rays
- All Subjects
- Physics
- Motion in a Plane
- Law of Motion
- Work, Energy and Power
- Systems of Particles and Rotational Motion
- Gravitation
- Mechanical Properties of Solids
- Mechanical Properties of Fluids
- Thermal Properties of matter
- Thermodynamics
- Kinetic Theory
- Oscillations
- Waves
- Electric Charge and Fields
- Electrostatic Potential and Capacitance
- Current Electricity
- Thermoelectric Effects of Electric Current
- Heating Effects of Electric Current
- Moving Charges and Magnetism
- Magnetism and Matter
- Electromagnetic Induction
- Alternating Current
- Electromagnetic Wave
- Ray Optics and Optical Instruments
- Wave Optics
- Dual Nature of Radiation and Matter
- Atoms
- Nuclei
- Semiconductor Electronics: Materials, Devices and Simple Circuits.
- Chemical Effects of Electric Current,