Why does the following reaction occur?

Question:

Why does the following reaction occur?

$\mathrm{XeO}_{6}^{4-}(\mathrm{aq})+2 \mathrm{~F}^{-}(\mathrm{aq})+6 \mathrm{H}^{+}(\mathrm{aq}) \rightarrow \mathrm{XeO}_{3}(\mathrm{~g})+\mathrm{F}_{2}(\mathrm{~g})+3 \mathrm{H}_{2} \mathrm{O}(\mathrm{l})$

What conclusion about the compound $\mathrm{Na}_{4} \mathrm{XeO}_{6}$ (of which $\mathrm{XeO}_{6}^{4-}$ is a part) can be drawn from the reaction.

Solution:

The given reaction occurs because $\mathrm{XeO}_{6}^{4}$ oxidises $\mathrm{F}^{-}$and $\mathrm{F}^{-}$reduces $\mathrm{XeO}_{6}^{4}$.

In this reaction, the oxidation number (O.N.) of Xe decreases from $+8$ in $\mathrm{XeO}_{6}^{4}$ to $+6$ in $\mathrm{XeO}_{3}$ and the $\mathrm{O} . \mathrm{N}$. of $\mathrm{F}$ increases from $-1$ in $\mathrm{F}^{-}$to $\mathrm{O}$ in $\mathrm{F}_{2}$.

Hence, we can conclude that $\mathrm{Na}_{4} \mathrm{XeO}_{6}$ is a stronger oxidising agent than $\mathrm{F}^{-}$.

 

Leave a comment

Close

Click here to get exam-ready with eSaral

For making your preparation journey smoother of JEE, NEET and Class 8 to 10, grab our app now.

Download Now