Question.
(i) Write the electronic configurations of the following ions:
(a) $\mathrm{H}^{-}$
(b) $\mathrm{Na}^{+}$
(c) $\mathrm{O}^{2-}$
(d) $\mathrm{F}^{-}$
(ii) What are the atomic numbers of elements whose outermost electrons are represented by
(a) $3 s^{1}$
(b) $2 p^{3}$ and
(c) $3 p^{5} ?$
(iii) Which atoms are indicated by the following configurations?
(a) $[\mathrm{He}] 2 s^{1}$
(b) [Ne] $3 s^{2} 3 p^{3}$
(c) $[\mathrm{Ar}] 4 s^{2} 3 d^{1}$.
(i) Write the electronic configurations of the following ions:
(a) $\mathrm{H}^{-}$
(b) $\mathrm{Na}^{+}$
(c) $\mathrm{O}^{2-}$
(d) $\mathrm{F}^{-}$
(ii) What are the atomic numbers of elements whose outermost electrons are represented by
(a) $3 s^{1}$
(b) $2 p^{3}$ and
(c) $3 p^{5} ?$
(iii) Which atoms are indicated by the following configurations?
(a) $[\mathrm{He}] 2 s^{1}$
(b) [Ne] $3 s^{2} 3 p^{3}$
(c) $[\mathrm{Ar}] 4 s^{2} 3 d^{1}$.
Solution:
(i) (a) $\mathbf{H}^{-}$ion
The electronic configuration of $\mathrm{H}$ atom is $1 \mathrm{~s}^{1}$.
A negative charge on the species indicates the gain of an electron by it
$\therefore$ Electronic configuration of $\mathrm{H}^{-}=1 s^{2}$
(b) $\mathrm{Na}^{+}$ion
The electronic configuration of Na atom is $1 s^{2} 2 s^{2} 2 p^{6} 3 s^{1}$.
A positive charge on the species indicates the loss of an electron by it.
$\therefore$ Electronic configuration of $\mathrm{Na}^{+}=1 s^{2} 2 s^{2} 2 p^{6} 3 s^{0}$ or $1 s^{2} 2 s^{2} 2 p^{6}$
(c) $\mathrm{O}^{2-}$ ion
The electronic configuration of 0 atom is $1 s^{2} 2 s^{2} 2 p^{4}$.
A dinegative charge on the species indicates that two electrons are gained by it
$\therefore$ Electronic configuration of $\mathrm{O}^{2-}$ ion $=1 s^{2} 2 s^{2} \mathrm{p}^{6}$
(d) $\mathrm{F}^{-}$ion
The electronic configuration of $\mathrm{F}$ atom is $1 s^{2} 2 s^{2} 2 p^{5}$.
A negative charge on the species indicates the gain of an electron by it.
$\therefore$ Electron configuration of $\mathrm{F}^{-}$ion $=1 s^{2} 2 s^{2} 2 p^{6}$
(ii) (a) $3 s^{1}$
Completing the electron configuration of the element as
$1 s^{2} 2 s^{2} 2 p^{6} 3 s^{1}$
Number of electrons present in the atom of the element
= 2 + 2 + 6 + 1 = 11
Atomic number of the element = 11
(b) $2 p^{3}$
Completing the electron configuration of the element as
$1 s^{2} 2 s^{2} 2 p^{3}$
Number of electrons present in the atom of the element = 2 + 2 + 3 = 7
Atomic number of the element = 7
(c) $3 p^{5}$
Completing the electron configuration of the element as
$1 s^{2} 2 s^{2} 2 p^{5}$
Number of electrons present in the atom of the element = 2 + 2 + 5 = 9
Atomic number of the element = 9
(iii) (a) [He] 2s $^{1}$
The electronic configuration of the element is [He] $2 s^{1}=1 s^{2} 2 s^{1}$.
Atomic number of the element = 3
Hence, the element with the electronic configuration [He] $2 s^{1}$ is lithium (Li).
(b) [Ne] $3 s^{2} 3 p^{3}$
The electronic configuration of the element is [Ne] $3 s^{2} 3 p^{3}=1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{3}$.
Atomic number of the element = 15
Hence, the element with the electronic configuration [Ne] $3 s^{2} 3 p^{3}$ is phosphorus (P).
(c) $[\mathrm{Ar}] 4 s^{2} 3 d^{1}$
The electronic configuration of the element is [Ar] $4 s^{2} 3 d^{1}=1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{2} 3 d^{1} . \therefore$
Atomic number of the element = 21
Hence, the element with the electronic configuration [Ar] $4 s^{2} 3 d^{1}$ is scandium (Sc).
(i) (a) $\mathbf{H}^{-}$ion
The electronic configuration of $\mathrm{H}$ atom is $1 \mathrm{~s}^{1}$.
A negative charge on the species indicates the gain of an electron by it
$\therefore$ Electronic configuration of $\mathrm{H}^{-}=1 s^{2}$
(b) $\mathrm{Na}^{+}$ion
The electronic configuration of Na atom is $1 s^{2} 2 s^{2} 2 p^{6} 3 s^{1}$.
A positive charge on the species indicates the loss of an electron by it.
$\therefore$ Electronic configuration of $\mathrm{Na}^{+}=1 s^{2} 2 s^{2} 2 p^{6} 3 s^{0}$ or $1 s^{2} 2 s^{2} 2 p^{6}$
(c) $\mathrm{O}^{2-}$ ion
The electronic configuration of 0 atom is $1 s^{2} 2 s^{2} 2 p^{4}$.
A dinegative charge on the species indicates that two electrons are gained by it
$\therefore$ Electronic configuration of $\mathrm{O}^{2-}$ ion $=1 s^{2} 2 s^{2} \mathrm{p}^{6}$
(d) $\mathrm{F}^{-}$ion
The electronic configuration of $\mathrm{F}$ atom is $1 s^{2} 2 s^{2} 2 p^{5}$.
A negative charge on the species indicates the gain of an electron by it.
$\therefore$ Electron configuration of $\mathrm{F}^{-}$ion $=1 s^{2} 2 s^{2} 2 p^{6}$
(ii) (a) $3 s^{1}$
Completing the electron configuration of the element as
$1 s^{2} 2 s^{2} 2 p^{6} 3 s^{1}$
Number of electrons present in the atom of the element
= 2 + 2 + 6 + 1 = 11
Atomic number of the element = 11
(b) $2 p^{3}$
Completing the electron configuration of the element as
$1 s^{2} 2 s^{2} 2 p^{3}$
Number of electrons present in the atom of the element = 2 + 2 + 3 = 7
Atomic number of the element = 7
(c) $3 p^{5}$
Completing the electron configuration of the element as
$1 s^{2} 2 s^{2} 2 p^{5}$
Number of electrons present in the atom of the element = 2 + 2 + 5 = 9
Atomic number of the element = 9
(iii) (a) [He] 2s $^{1}$
The electronic configuration of the element is [He] $2 s^{1}=1 s^{2} 2 s^{1}$.
Atomic number of the element = 3
Hence, the element with the electronic configuration [He] $2 s^{1}$ is lithium (Li).
(b) [Ne] $3 s^{2} 3 p^{3}$
The electronic configuration of the element is [Ne] $3 s^{2} 3 p^{3}=1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{3}$.
Atomic number of the element = 15
Hence, the element with the electronic configuration [Ne] $3 s^{2} 3 p^{3}$ is phosphorus (P).
(c) $[\mathrm{Ar}] 4 s^{2} 3 d^{1}$
The electronic configuration of the element is [Ar] $4 s^{2} 3 d^{1}=1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{2} 3 d^{1} . \therefore$
Atomic number of the element = 21
Hence, the element with the electronic configuration [Ar] $4 s^{2} 3 d^{1}$ is scandium (Sc).
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