Question:
Write the Nernst equation for the cell reaction in the Daniel cell. How will the ECell be affected when the concentration of Zn2+ ions is increased?
Solution:
Ecell = E°cell – RT[Zn2+]/ nF[Cu2+]
Galvanic cell reaction: Zn(s)|Zn2+(aq)||Cu2+(aq)|Cu(s)
Anode- oxidation half-cell: Zn(s) → Zn2+ (aq)+ 2e
Cathode- reduction half-cell: Cu2+ (aq)+ 2e-→ Cu(s)
Overall reaction: Zn(s) + Cu2+ (aq) → Zn2+(aq) +Cu(s)
[Zn2+] and [Cu2+] are the concentration of the Zn2+ and Cu2+ ion in the solution.
Ecell = E°cell – 0.059/2[Zn2+]/[Cu2+]
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- JEE Main
- Exam Pattern
- Previous Year Papers
- PYQ Chapterwise
- Physics
- Kinematics 1D
- Kinemetics 2D
- Friction
- Work, Power, Energy
- Centre of Mass and Collision
- Rotational Dynamics
- Gravitation
- Calorimetry
- Elasticity
- Thermal Expansion
- Heat Transfer
- Kinetic Theory of Gases
- Thermodynamics
- Simple Harmonic Motion
- Wave on String
- Sound waves
- Fluid Mechanics
- Electrostatics
- Current Electricity
- Capacitor
- Magnetism and Matter
- Electromagnetic Induction
- Atomic Structure
- Dual Nature of Matter
- Nuclear Physics
- Radioactivity
- Semiconductors
- Communication System
- Error in Measurement & instruments
- Alternating Current
- Electromagnetic Waves
- Wave Optics
- X-Rays
- All Subjects
- Physics
- Motion in a Plane
- Law of Motion
- Work, Energy and Power
- Systems of Particles and Rotational Motion
- Gravitation
- Mechanical Properties of Solids
- Mechanical Properties of Fluids
- Thermal Properties of matter
- Thermodynamics
- Kinetic Theory
- Oscillations
- Waves
- Electric Charge and Fields
- Electrostatic Potential and Capacitance
- Current Electricity
- Thermoelectric Effects of Electric Current
- Heating Effects of Electric Current
- Moving Charges and Magnetism
- Magnetism and Matter
- Electromagnetic Induction
- Alternating Current
- Electromagnetic Wave
- Ray Optics and Optical Instruments
- Wave Optics
- Dual Nature of Radiation and Matter
- Atoms
- Nuclei
- Semiconductor Electronics: Materials, Devices and Simple Circuits.
- Chemical Effects of Electric Current,
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